Reaktion #75022

ord-3c2d463041064f17a5965d17a1397be7

Reaktionsgleichung

C=CCCCCCC
Octene-1
CC(=O)[O-].[K+]
potassium acetate
→
CCCCCCC1CCC(=O)O1
gamma-n-hexyl-butyrolactone
Ausbeute 74.0%

Edukte

C=CCCCCCC
Octene-1
—
MnO2.4H2O
CC(=O)[O-].[K+]
potassium acetate

Reagenzien

Keine

Lösungsmittel

CC(=O)O
acetic acid

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    Temperaturheated under nitrogen in 300 ml

Vorschrift

Octene-1 in an amount of 3.37 g. and 4.8 g. of freshly prepared MnO2.4H2O were mixed with and heated under nitrogen in 300 ml. glacial acetic acid containing 90 g. potassium acetate. After a reaction time of less than two hours, gamma-n-hexyl-butyrolactone was obtained in 74% yield.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US04175089uspto-grants-1979_11