Reaktion #74685

Reaktionsgleichung

tri(n-butyl)phosphine

chloromethyl 4-chlorophenyl sulfide

→

Tributyl((4-chlorophenylthio)methyl)phosphonium chloride

Lösungsmittel

hexane

p-dioxane

Reaktionsbedingungen

Aufarbeitung

1. 1
   Temperaturrefluxed (101°-102° C.) for 20 hours
2. 2
   FiltrationThe white precipitate was filtered
3. 3
   Sonstigedried
4. 4
   Sonstigeto give 1

Vorschrift

A solution of 8.45 g of tri(n-butyl)phosphine and 8.33 g of chloromethyl 4-chlorophenyl sulfide in 25 ml of p-dioxane was stirred and refluxed (101°-102° C.) for 20 hours. The mixture was cooled to room temperature and diluted with 100 ml of hexane. The white precipitate was filtered and dried to give 1, as a solid, mp 113°-114° C.

Quelle