Reaktion #736834

ord-d44b41bb874b4ae1a30ab51a64791420

Reaktionsgleichung

[K+].[OH-]
potassium hydroxide
OCCO
ethylene glycol
O=[N+]([O-])c1cc2c(cc1[N+](=O)[O-])OCO2
4,5-methylenedioxy-1,2-dinitrobenzene
→
O=[N+]([O-])c1cc(O)c(OCCO)cc1[N+](=O)[O-]
4,5-dinitro-2-(β-hydroxyethoxy)phenol

Edukte

[K+].[OH-]
potassium hydroxide
OCCO
ethylene glycol
O=[N+]([O-])c1cc2c(cc1[N+](=O)[O-])OCO2
4,5-methylenedioxy-1,2-dinitrobenzene

Reagenzien

Keine

Reaktionsbedingungen

Temperatur
50°CELSIUS
Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    TemperaturThe heating is maintained for 2 hours

Vorschrift

0.2 mol (13.2 g) of potassium hydroxide pellets (85%) is added to 100 ml of ethylene glycol which has been heated beforehand at 50° C. 0.1 mol (21.2 g) of 4,5-methylenedioxy-1,2-dinitrobenzene is added in a single portion to this solution. The heating is maintained for 2 hours.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US04740622uspto-grants-1988_04