Reaktion #7363

Reaktionsgleichung

sodium hydroxide

diethyl sulfate

triethyl amine

ethanol

→

tetraethyl ammonium hydroxide

Reaktionsbedingungen

Aufarbeitung

1. 1
   SonstigeTo a 1.5 L autoclave equipped with a stirrer
2. 2
   Sonstigewas sealed
3. 3
   TemperaturThen the reaction mixture was cooled to room temperature
4. 4
   Sonstigedischarged into a 1 L three-necked flask
5. 5
   TemperaturThe reaction mixture was heated to 45° C. for 4 h
6. 6
   workup.STIRRINGwhile stirring
7. 7
   FiltrationAfter filtration, part of ethanol
8. 8
   workup.DISTILLATIONwas distilled off from the filtrate
9. 9
   workup.ADDITIONThen 500 g of water was added while ethanol
10. 10
    workup.DISTILLATIONwas distilled off (part of water was entrained out)

Vorschrift

To a 1.5 L autoclave equipped with a stirrer and a heating means were added 154 g (1.0 mol) of diethyl sulfate, 101 g (1.0 mol) of triethyl amine and 690 g (15 mol) of ethanol. Stirring was initiated after the autoclave was sealed. The autoclave was heat to 140° C., and pressure was 1.0 MPa. The reaction was kept at 140° C. for 4 h. Then the reaction mixture was cooled to room temperature and discharged into a 1 L three-necked flask. 80 g (2.0 mol) of sodium hydroxide was added thereto. The reaction mixture was heated to 45° C. for 4 h while stirring. After filtration, part of ethanol was distilled off from the filtrate. Then 500 g of water was added while ethanol was distilled off (part of water was entrained out), to give 604 g of tetraethyl ammonium hydroxide solution. The content of tetraethyl ammonium hydroxide was found as 23.3 wt.-% and the total reaction yield was 95.7%.

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