Reaktion #715757

Reaktionsgleichung

3′-Fluoro-3,4′-dinitrobiphenyl-4-amine

K2CO3

MeNH2

→

product

Ausbeute 100.0%

N3-Methyl-3′,4-dinitrobiphenyl-3,4′-diamine

Ausbeute 100.0%

Lösungsmittel

DCM

Reaktionsbedingungen

Aufarbeitung

1. 1
   WaschenThe solution was then washed with H2O and brine
2. 2
   TrocknenThe organic layer was dried (MgSO4)
3. 3
   Filtrationfiltered
4. 4
   Einengenconcentrated in vacuo

Vorschrift

3′-Fluoro-3,4′-dinitrobiphenyl-4-amine (285 mg, 1.03 mmol) was suspended in DCM (10 mL). K2CO3 (284 mg, 2.06 mmol) was added, followed by MeNH2 (40% in H2O, 10 mL). The mixture was stirred at room temperature for 72 h. The solution was then washed with H2O and brine. The organic layer was dried (MgSO4), filtered and concentrated in vacuo to afford the product as a red solid (296 mg, 100%).

Quelle