Reaktion #707641

ord-81048ea7faf3483092d2da47a242376d

Reaktionsgleichung

CC(C)C(O)C(C)(C)CO
2,2,4-trimethyl-1,3-dihydroxypentane
O=[N+]([O-])c1ccc(Cl)cc1
4-nitrochlorobenzene
[Na+].[OH-]
sodium hydroxide
→
CC(C)C(Oc1ccc([N+](=O)[O-])cc1)C(C)(C)COc1ccc([N+](=O)[O-])cc1
1,3-bis-(4-nitrophenoxy)-2,2,4-trimethylpentane

Edukte

CC(C)C(O)C(C)(C)CO
2,2,4-trimethyl-1,3-dihydroxypentane
O=[N+]([O-])c1ccc(Cl)cc1
4-nitrochlorobenzene
[Na+].[OH-]
sodium hydroxide

Reagenzien

Keine

Lösungsmittel

CS(C)=O
DMSO

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    Sonstigewere reacted

Vorschrift

146 g (1 mol) 2,2,4-trimethyl-1,3-dihydroxypentane, 346.5 g (2.2 mols) 4-nitrochlorobenzene and 140 g powdered sodium hydroxide were reacted using the same procedure described in Example 1 in 600 ml DMSO.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US04820866uspto-grants-1989_04