Reaktion #703954

ord-6c68d8dc0d42425b9fd10b7c33033f11

Reaktionsgleichung

O=C(O)CCC1(c2ccccc2)SCCS1
2-phenyl-1,3-dithiolane-2-propionic acid
CC(S)S
ethanedithiol
O=C(O)CCC(=O)c1ccccc1
4-phenyl-4-oxobutyric acid
CC(S)C(C)S
2,3-butanedithiol
CC(S)CS
1,2-propanedithiol

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

In the same manner, 4-phenyl-4-oxobutyric acid is converted to 2-phenyl-1,3-dithiolane-2-propionic acid using ethanedithiol; while the use of 1,2-propanedithiol and 2,3-butanedithiol affords 4-methyl- and 4,5-dimethyl-2-phenyl-1,3-dithiolane-2-propionic acid, respectively.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US04075228uspto-grants-1978_02