Reaktion #696696

Reaktionsgleichung

hydrogen chloride

2-methyl-2-pentene

iso-amyl nitrite

→

2-Chloro-2-methyl-3-nitrosopentane

Reaktionsbedingungen

Aufarbeitung

1. 1
   workup.WAITThe reaction mixture was left
2. 2
   Filtrationthe precipitated material was then filtered off
3. 3
   Waschenwashed with cold (-20° C.) ethanol (3×5 ml)
4. 4
   SonstigeThe product was dried in a stream of air
5. 5
   Sonstigewas used without further purification, (13 g, 36%)

Vorschrift

Dry hydrogen chloride gas was passed into a mixture of 2-methyl-2-pentene (20 g, 237 mmol) and iso-amyl nitrite (55.67 g, 475 mmol) cooled to -20° C. The reaction mixture was left to stir at 0° C. overnight and the precipitated material was then filtered off and washed with cold (-20° C.) ethanol (3×5 ml). The product was dried in a stream of air and was used without further purification, (13 g, 36%).

Quelle