Reaktion #668161

Reaktionsgleichung

Methyl 2-methyl-3-(4-allyloxyphenyl)propionate

4-hydroxyphenylpropionate

methyl 2-methyl-3-(4-allyloxyphenyl)propionate

ethyl 3-(3-allyl-4-hydroxyphenyl)propionate

ethyl 3-(4-allyloxyphenyl)propionate

→

Methyl 2-methyl-3-(3-allyl-4-hydroxyphenyl)propionate

Reaktionsbedingungen

Aufarbeitung

1. 1
   SonstigeThe product was isolated as an orange oil

Vorschrift

Methyl 2-methyl-3-(4-allyloxyphenyl)propionate m/z 235(M+H) was prepared from methyl 2-methyl-3-(4-hydroxyphenylpropionate using the method described in Example 1 for the preparation of ethyl 3-(4-allyloxyphenyl)propionate. Methyl 2-methyl-3-(3-allyl-4-hydroxyphenyl)propionate was prepared from methyl 2-methyl-3-(4-allyloxyphenyl)propionate using the method described in Example 1 for the preparation of ethyl 3-(3-allyl-4-hydroxyphenyl)propionate. The product was isolated as an orange oil; NMR(CDCl3): 1.13(3H,d), 2.40-2.73(2H,m), 2.92(1H,q), 3.37(2H,d), 3.63(3H,s), 4.91(1H,s), 5.03-5.18(2H,m), 5.89-6.10(1H,m), 6.70(1H,m) and 6.91(2H,m); m/z 235(M+H).

Quelle