Reaktion #6540

ord-bbaa095270804d84806076369776a1e2

Reaktionsgleichung

C1=CCCC1
cyclopentene
Cl[SiH](Cl)Cl
trichlorosilane
CC(C)O
isopropyl alcohol
→
Cl[Si](Cl)(Cl)C1CCCC1
Cyclopentyl trichlorosilane

Edukte

C1=CCCC1
cyclopentene
Cl[SiH](Cl)Cl
trichlorosilane
CC(C)O
isopropyl alcohol

Reagenzien

[Cl][Pt-2]([Cl])([Cl])([Cl])([Cl])[Cl].[H+].[H+]
chloroplatinic acid

Reaktionsbedingungen

Temperatur
150°CELSIUS
Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

In a 100 ml autoclave were charged 16.7 g (0.245 mole) of cyclopentene, 30.1 g (0.222 mole) of trichlorosilane and 25 μl of a 0.077 m mole/ml chloroplatinic acid solution in isopropyl alcohol (platinum content 1.92×10-6 mole), which were then stirred at 150° C. for 30 minutes. Cyclopentyl trichlorosilane was obtained quantitatively.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US05248803uspto-grants-1993_09