Reaktion #6425

ord-ea88f85ac3924f1abb143061996c57cd

Reaktionsgleichung

CC(C)(C)C(N)C(N)=O
DL-tertiary leucine amide
CC(C)(C)[C@H](N)C(=O)O
L-tertiary leucine
CC(C)(C)[C@@H](N)C(N)=O
D-tertiary leucine amide
→
CC(C)(C)[C@H](N)C(N)=O
tertiary leucine amide

Edukte

CC(C)(C)C(N)C(N)=O
DL-tertiary leucine amide
CC(C)(C)[C@H](N)C(=O)O
L-tertiary leucine
CC(C)(C)[C@@H](N)C(N)=O
D-tertiary leucine amide

Reagenzien

Keine

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    SonstigeAnalysis of the remaining reaction mixture after 8 hours

Vorschrift

In the same way as in example VIII, an incubation was carried out with DL-tertiary leucine amide. Analysis of the remaining reaction mixture after 8 hours showed that both L-tertiary leucine and D-tertiary leucine amide with an e.e. of ≥99% were present in the reaction mixture.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US05248608uspto-grants-1993_09