Reaktion #64245

ord-b24ebc5c9e1b4814845e2e28f2770630

Reaktionsgleichung

CN(C=O)[C@H]1CC[C@H](O[N+](=O)[O-])CC1
trans-N-methyl-N-formyl-4-nitroxycyclohexylamine
CN[C@H]1CC[C@H](O[N+](=O)[O-])CC1
trans-N-methyl-4-nitroxycyclohexylamine
→
O=CN[C@H]1CC[C@H](O[N+](=O)[O-])CC1
trans-N-formyl-4-nitroxycyclohexylamine
Ausbeute 60.0%

Edukte

CN(C=O)[C@H]1CC[C@H](O[N+](=O)[O-])CC1
trans-N-methyl-N-formyl-4-nitroxycyclohexylamine
CN[C@H]1CC[C@H](O[N+](=O)[O-])CC1
trans-N-methyl-4-nitroxycyclohexylamine

Reagenzien

Keine

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

trans-N-methyl-N-formyl-4-nitroxycyclohexylamine from trans-N-methyl-4-nitroxycyclohexylamine melting point: 52°-54° C. (ether/isohexane), yield: 60% of theory.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US05411989uspto-grants-1995_05