Reaktion #63436

ord-9b579c6ea71c44829cf397c559a47b98

Reaktionsgleichung

N#CN1Cc2ccccc2-c2ccccc2C1
5,7-dihydro-6H-dibenz[c,e]azepine-6-carbonitrile
CC[S-].[Na+]
sodium ethanethiolate
CCSC(=N)N1Cc2ccccc2-c2ccccc2C1
ethyl 5,7-dihydro-6H-dibenz[c,e]azepine-6-thiocarboximidate

Lösungsmittel

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

starting from 5,7-dihydro-6H-dibenz[c,e]azepine-6-carbonitrile and sodium ethanethiolate in ethanethiol there is obtained ethyl 5,7-dihydro-6H-dibenz[c,e]azepine-6-thiocarboximidate and therefrom with hydrochloric acid in alcohol there is obtained the hydrochloride, m.p. 220° C. (with decomposition);

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US04766115uspto-grants-1988_08