Reaktion #63330

ord-8e99aae1d1e04736be34c3bafe85fee5

Reaktionsgleichung

CSC(=NC#N)SC
N-cyano-carbonimidodithioic acid dimethyl ester
NCCCOc1cccc(CN2CCCC2)c1
3-[3-(1-pyrrolidinylmethyl)phenoxy]propanamine
CSC(=NC#N)NCCCOc1cccc(CN2CCCC2)c1
title compound
CSC(=NC#N)NCCCOc1cccc(CN2CCCC2)c1
N'-Cyano-N-[3-[3-(1-pyrrolidinylmethyl)phenoxy]propyl]carbamimidothioic acid, methyl ester

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

A solution of N-cyano-carbonimidodithioic acid dimethyl ester (5 g) in ethyl acetate (50 ml) was added to a solution of 3-[3-(1-pyrrolidinylmethyl)phenoxy]propanamine in ethyl acetate (60 ml). The reaction mixture was stirred at room temperature for 1 hr to give the title compound as an off-white solid m.p. 107°-108.5° (7.45 g). TLC silica; ethyl acetate: isopropanol:water:0.88 ammonia (25:15:8:2) single spot Rf 0.7.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US04764612uspto-grants-1988_08