Reaktion #63293

ord-1bf441c637544fe88729dd31b7ab1c65

Reaktionsgleichung

O=Cc1ccco1
Furfural
CO
methanol
Cc1ccco1.Cc1ccoc1C.c1ccoc1
furan methylfuran dimethylfuran

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    Sonstigefor a residence time of about 1 second
  2. 2
    SonstigeThe resultant vapor was collected

Vorschrift

Furfural aldehyde and methanol were co-fed in equal amounts over a ZSM-5 zeolite catalyst at atmospheric pressure and at about 500° C. temperature for a residence time of about 1 second. The WHSV ratio was about 25 for each species in the feedstock vapor. The resultant vapor was collected and tested and resulted in a furan/methylfuran/dimethylfuran product ratio of about 5.6/2/1. Therefore, co-feeidng methanol produced substantial methylation of the furan product.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US04764627uspto-grants-1988_08