Reaktion #63291

ord-05bdd44fe3d447eaafc64f1cc325b326

Reaktionsgleichung

Ic1ccccc1
iodobenzene
c1ccc(Nc2ccccc2)cc1
diphenylamine
[K+].[OH-]
potassium hydroxide
→
c1ccc(N(c2ccccc2)c2ccccc2)cc1
triphenylamine
Ausbeute 82.0%

Edukte

Ic1ccccc1
iodobenzene
c1ccc(Nc2ccccc2)cc1
diphenylamine
[K+].[OH-]
potassium hydroxide

Reagenzien

[Cu]
copper

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    workup.ADDITIONfollowing charge
  2. 2
    SonstigeThe above-identified product was obtained as colorless crystals

Vorschrift

The same equipment and conditions as in example I were employed with the following charge: 20.4 grams (0.1 mole) iodobenzene, 27.4 grams (0.15 mole) diphenylamine, 16.8 grams (0.3 mole) potassium hydroxide flakes, 15.0 grams of copper powder and 30.0 milliliters of Soltrol® 170. The above-identified product was obtained as colorless crystals having a melting point of 125°-126° C. Yield 82%.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US04764625uspto-grants-1988_08