Reaktion #6299

Reaktionsgleichung

4-triflyltoluene

N-bromosuccinimide

benzoyl peroxide

→

4-Triflyl-alpha-bromotoluene

Lösungsmittel

carbon tetrachloride

carbon tetrachloride

Reaktionsbedingungen

Aufarbeitung

1. 1
   Temperaturat reflux for 20 hours
2. 2
   Sonstigethe solid byproducts are removed by filtration
3. 3
   EinengenThe filtrate is concentrated in vacuo
4. 4
   Sonstigethe product is purified by recrystallization from benzene

Vorschrift

A stirred solution of 22.4 g (0.1 mole) of 4-triflyltoluene, 178 g (0.1 mole) of N-bromosuccinimide, and 0.48 g (0.2 mole %) of benzoyl peroxide in carbon tetrachloride is heated at reflux for 20 hours. After cooling to room temperature, the reaction is diluted by the addition of carbon tetrachloride, and the solid byproducts are removed by filtration. The filtrate is concentrated in vacuo, and the product is purified by recrystallization from benzene.

Quelle