Reaktion #62970

ord-01f407b26c404daab6db59143a8e4364

Reaktionsgleichung

OCC(O)CBr
bromomethyl ethylene glycol
O=S(=O)([O-])[O-].[Mg+2]
magnesium sulfate
CC(C)=O
acetone
→
CC1(C)OCC(CBr)O1
crude product
CC1(C)OCC(CBr)O1
2,2-Dimethyl-4-bromomethyl-1,3-dioxolane

Edukte

OCC(O)CBr
bromomethyl ethylene glycol
O=S(=O)([O-])[O-].[Mg+2]
magnesium sulfate
CC(C)=O
acetone

Reagenzien

Keine

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    SonstigeThe cooled reaction mixture
  2. 2
    Filtrationis filtered
  3. 3
    Sonstigethe solvent is removed

Vorschrift

An acetone solution of bromomethyl ethylene glycol is refluxed for 24 hours in the presence of anhydrous magnesium sulfate. The cooled reaction mixture is filtered and the solvent is removed to provide a residual crude product.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US04762912uspto-grants-1988_08