Reaktion #626625

ord-551f778a06bd43feb56a620e4a911f70

Reaktionsgleichung

O=S(=O)([O-])OOS(=O)(=O)[O-].[NH4+].[NH4+]
ammonium persulfate
[Na]
sodium
C1CO1.C=C(C)C(=O)O
methacrylic acid ethylene oxide
C=Cc1ccccc1
styrene
C=C(C)C(=O)O
methacrylic acid
C=CC(=O)OCCCC
butyl acrylate
O=S(=O)([O-])OOS(=O)(=O)[O-].[NH4+].[NH4+]
ammonium persulfate
→
C=C(CC=Cc1ccccc1)C(=O)[O-].C=CC(=O)OCCCC.[Na]
styrene-methacrylate butyl acrylate sodium
C1CO1.C=C(C)C(=O)O
methacrylic acid ethylene oxide

Edukte

O=S(=O)([O-])OOS(=O)(=O)[O-].[NH4+].[NH4+]
ammonium persulfate
—
polylactic acid
[Na]
sodium
C1CO1.C=C(C)C(=O)O
methacrylic acid ethylene oxide
C=Cc1ccccc1
styrene
C=C(C)C(=O)O
methacrylic acid
C=CC(=O)OCCCC
butyl acrylate
O=S(=O)([O-])OOS(=O)(=O)[O-].[NH4+].[NH4+]
ammonium persulfate

Reagenzien

Keine

Lösungsmittel

O
water

Reaktionsbedingungen

Temperatur
75°CELSIUS
Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    SonstigeInto a reaction vessel equipped with a stirring rod
  2. 2
    Sonstigeto thereby obtain a white emulsion
  3. 3
    Temperaturby heating
  4. 4
    Sonstigereacted for 4 hours
  5. 5
    workup.WAITaged at 75° C. for 6 hours

Vorschrift

Into a reaction vessel equipped with a stirring rod and a thermometer, 683 parts by mass of water, 11 parts by mass of sodium salt of methacrylic acid ethylene oxide adduct sulfate ester (ELEMINOL RS-30, manufactured by Sanyo Chemical Industries, Ltd.), 10 parts by mass of polylactic acid, 60 parts by mass of styrene, 100 parts by mass of methacrylic acid, 70 parts by mass of butyl acrylate, and 1 part by mass of ammonium persulfate were charged and then stirred at 3,800 rpm for 30 minutes, to thereby obtain a white emulsion. Then, the temperature of the reaction system was raised to 75° C. by heating and reacted for 4 hours. Further, 30 parts by mass of a 1% by mass aqueous ammonium persulfate solution was added to the reaction system and aged at 75° C. for 6 hours to thereby obtain an aqueous dispersion liquid of a vinyl resin (a copolymer of styrene-methacrylate-butyl acrylate-sodium salt of methacrylic acid ethylene oxide adduct sulfate ester), i.e., Fine Particle Dispersion Liquid 5. The volume average particle diameter of Fine Particle Dispersion Liquid 5 was 105 nm as measured with a particle size distribution measurement device (LA-920, manufactured by HORIBA, Ltd.). A part of Fine Particle Dispersion Liquid 5 was dried so that the resin part was isolated therefrom. The resin part had Tg of 58° C., and a weight average molecular weight of 140,000.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US08871418B2uspto-grants-2014_10