Reaktion #621963

Reaktionsgleichung

2-chloro-4-nitrotoluene

N-bromosuccinimide

→

oil/solid

Ausbeute 133.4%

1-(Bromomethyl)-2-chloro-4-nitrobenzene

Ausbeute 133.4%

Lösungsmittel

tetrachloromethane

Reaktionsbedingungen

Aufarbeitung

1. 1
   Sonstigewas irradiated (500 W lamp)
2. 2
   Temperaturat reflux overnight
3. 3
   EinengenThe reaction mixture was concentrated

Vorschrift

A mixture of 2-chloro-4-nitrotoluene (0.20 g, 1.17 mmol), N-bromosuccinimide (0.228 g, 1.28 mmol) and benzoyl peroxide (0.014 g, 0.058 mmol) in tetrachloromethane (7 mL) was irradiated (500 W lamp) at reflux overnight. The reaction mixture was concentrated to give a yellow oil/solid (0.391 g) which was used directly in the next step without further purification.

Quelle