Reaktion #61886

ord-7d1005021b344960abba0f2bfa216f2f

Reaktionsgleichung

C=CC(=C)C
isoprene
C=CC=O
acrolein
→
CC1=CCC(CO)CC1
4-methyl-3-cyclohexenylmethanol

Edukte

C=CC(=C)C
isoprene
C=CC=O
acrolein
—
4-methyl-3-cyclohexenyl aldehyde

Reagenzien

Keine

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    SonstigeAccording to the well known Diels-Alder Reaction
  2. 2
    Sonstigewas synthesized

Vorschrift

According to the well known Diels-Alder Reaction, using isoprene and acrolein as raw materials, 4-methyl-3-cyclohexenyl aldehyde was synthesized. The reaction was conducted under the conditions described in the literary documents of J. Amer, Chem. Soc., 119, 15, 1997, 3507-3512; and Tetrahedron Lett., 40, 32, 1999, 5817-5822. Subsequently, the compound was reduced to obtain 4-methyl-3-cyclohexenylmethanol at a high yield.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US07429622B2uspto-grants-2008_09