Reaktion #6109

ord-be2199f40d44415e9d6c4b76de61d7c9

Reaktionsgleichung

CN(C)C(=S)Cl
dimethylthiocarbamoyl chloride
Oc1ccccc1C(F)(F)F
2-tri-fluoromethylphenol
[K+].[OH-]
potassium hydroxide
CN(C)C(=S)Oc1ccccc1C(F)(F)F
yellow oil
Ausbeute 89.0%
CN(C)C(=S)Oc1ccccc1C(F)(F)F
O-2-trifluoromethylphenyl dimethylthiocarbamate
Ausbeute 89.0%

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

If the procedure described in Preparation XI is followed starting from 3.95 g (24.3.10-3 mol) of 2-tri-fluoromethylphenol, 1.43 g (25.6.10-3 mol) of potassium hydroxide and 3.46 g (28.10-3 mol) of dimethylthiocarbamoyl chloride, 5.37 g (yield: 89%) of a yellow oil are obtained.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US05246961uspto-grants-1993_09