Reaktion #60231

Reaktionsgleichung

N,N-bis[4″-(N-phenyl-1-naphthylamino)-p-terphenyl-4-yl]acetamide

potassium hydroxide

diethylbenzene

water

→

N,N-bis[4″-(N-phenyl-1-naphthylamino)-p-terphenyl-4-yl]amine

Ausbeute 85.5%

Lösungsmittel

hexane

Reaktionsbedingungen

Aufarbeitung

1. 1
   workup.ADDITIONCharged
2. 2
   Temperaturrefluxed for 3 days
3. 3
   Sonstigethe reaction
4. 4
   workup.WAITthe mixture was left
5. 5
   Temperaturcooling down
6. 6
   FiltrationThe brown solid matter deposited was filtered off
7. 7
   Sonstigedried under reduced pressure

Vorschrift

Charged were N,N-bis[4″-(N-phenyl-1-naphthylamino)-p-terphenyl-4-yl]acetamide 82.0 g, a 50% potassium hydroxide aqueous solution 39 g and diethylbenzene 100 ml, and the mixture was heated and refluxed for 3 days. After finishing the reaction, the mixture was left cooling down, and water 100 ml and hexane 500 ml were added thereto. The brown solid matter deposited was filtered off and dried under reduced pressure to obtain 67 g of N,N-bis[4″-(N-phenyl-1-naphthylamino)-p-terphenyl-4-yl]amine.

Quelle