Reaktion #6016

ord-20f53bdf122d4c0eb79fea6119fe9f55

Reaktionsgleichung

O=C(c1ccccc1)c1ccc2c(c1)[Se](=O)C=N2
6-benzoylbenzoselenazolinone
→
Nc1ccc(C(=O)c2ccccc2)cc1[Se][Se]c1cc(C(=O)c2ccccc2)ccc1N
BIS(2-AMINO-5-BENZOYLPHENYL) DISELENIDE

Edukte

O=C(c1ccccc1)c1ccc2c(c1)[Se](=O)C=N2
6-benzoylbenzoselenazolinone

Reagenzien

Keine

Lösungsmittel

[Na+].[OH-]
sodium hydroxide

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    TemperaturThe mixture is heated
  2. 2
    Temperaturto reflux
  3. 3
    TemperaturAfter cooling
  4. 4
    Waschenwashed with water
  5. 5
    Sonstigedried
  6. 6
    Sonstigethe product is recrystallized in toluene

Vorschrift

1.5 g (0.005 mol) of 6-benzoylbenzoselenazolinone are introduced together with 20 cm3 of 10% sodium hydroxide into a ground-necked flask. The mixture is heated to reflux with stirring for two hours. After cooling, the reaction medium is neutralized. The precipitate is drained, washed with water and dried and the product is recrystallized in toluene.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US05246951uspto-grants-1993_09