Reaktion #59935

Reaktionsgleichung

tetrahydrofuran

methyl(2-ethyl-1,3-dioxolan-2-yl) acetate

potassium carbonate

→

title compound

Ausbeute 71.5%

(2-ethyl-1,3-dioxolan-2-yl)methanol

Ausbeute 71.5%

Lösungsmittel

water

Reaktionsbedingungen

Aufarbeitung

1. 1
   EinengenThe reaction mixture was concentrated under reduced pressure, ethyl acetate
2. 2
   workup.ADDITIONwas added to the residue, which
3. 3
   Filtrationwas subjected to NH silica gel pad filtration
4. 4
   EinengenThe filtrate was concentrated under reduced pressure

Vorschrift

A mixture of methyl(2-ethyl-1,3-dioxolan-2-yl) acetate (1.39 g, 7.94 mmol), potassium carbonate (2.19 g, 15.9 mmol), tetrahydrofuran (20 ml) and water (10 ml) was stirred at room temperature for 6 hours and 50 minutes. The reaction mixture was concentrated under reduced pressure, ethyl acetate was added to the residue, which was subjected to NH silica gel pad filtration. The filtrate was concentrated under reduced pressure to obtain the title compound (0.75 g, 71.5%) as colorless oil.

Quelle