Reaktion #59639

Reaktionsgleichung

tert-butyl vinyl ether

vinyl ether

dimethylphenylsilane

silane

tert-butyl ether

→

Butyl Ether

Lösungsmittel

1,4-dioxane

Reaktionsbedingungen

Aufarbeitung

1. 1
   SonstigeInto a 30 ml round-bottom flask with two necks equipped with a three-way cock, in which the air
2. 2
   workup.DISTILLATIONthe 1,4-dioxane and the excess phenyldimethyl silane were distilled off
3. 3
   workup.DISSOLUTIONInto the residual viscous liquid was dissolved in 2 ml of hexane
4. 4
   workup.ADDITIONthe addition of methanol 6 ml
5. 5
   Sonstigeto drying in vacuo
6. 6
   Sonstigeto yield a white solid material, 277 mg (92%)
7. 7
   SonstigeFrom these results the white solid material

Vorschrift

Into a 30 ml round-bottom flask with two necks equipped with a three-way cock, in which the air had been replaced with nitrogen gas, there were added 2.15 mg (3.3×10−3 mmol) of acenaphthylene heptacarbonyl ruthenium (the polynuclear ruthenium-carbonyl complex as expressed by the formula (V): hereinafter sometimes referred to simply as the “Ru complex”) as the catalyst, 0.05 ml of 1,4-dioxane as the solvent, and 0.050 ml (0.33 mmol) of dimethylphenylsilane (HSiMe2Ph) as the silane compound. After stirring at room temperature (25° C.) for thirty minutes, there was added 0.43 ml (3.3 mmol) of tert-butyl vinyl ether (tBuVE) as the vinyl ether compound. The resultant solution was stirred at room temperature for ten minutes, and then the 1,4-dioxane and the excess phenyldimethyl silane were distilled off. Into the residual viscous liquid was dissolved in 2 ml of hexane. Following the addition of methanol 6 ml, the resultant white deposit was subjected to drying in vacuo, to yield a white solid material, 277 mg (92%). The molecular weight of the white solid material was determined by GPC, and the material was also subjected to the measurement of IR, 1H and 13C NMR spectra. FIG. 2 shows the GPC chart. The assignment of the IR and NMR data are summarized below. From these results the white solid material was identified to be polyvinyl tert-butyl ether.

Quelle