Reaktion #578433

ord-56c73c674f6e45feb107ca90d3d30919

Reaktionsgleichung

C=Cc1ccc(Br)cc1
4-bromostyrene
C=CC=O
acrolein
C=C(C)C(=O)[O-]
methacrylate
CC(C)(C#N)N=NC(C)(C)C#N
AIBN
COCC(C)OC(C)=O
PGMEA
→
BrC=Cc1ccccc1.C=C(C)C(=O)[O-].C=CC=O
bromostyrene acrolein methacrylate

Edukte

C=Cc1ccc(Br)cc1
4-bromostyrene
C=CC=O
acrolein
C=C(C)C(=O)[O-]
methacrylate
CC(C)(C#N)N=NC(C)(C)C#N
AIBN
COCC(C)OC(C)=O
PGMEA

Reagenzien

Keine

Reaktionsbedingungen

Temperatur
67°CELSIUS
Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    SonstigeThe mixture was polymerized
  2. 2
    SonstigeAfter completion of the polymerization
  3. 3
    Sonstigethe polymerization product was precipitated in n-hexane
  4. 4
    Filtrationfiltered
  5. 5
    Sonstigedried in vacuo

Vorschrift

3 g of 4-bromostyrene, 4 g of acrolein, 3 g of methacrylate and 0.2 g of AIBN were sufficiently mixed with 50 g of PGMEA. The mixture was polymerized by heating the mixture at 67° C. for 8 hours. After completion of the polymerization, the polymerization product was precipitated in n-hexane, filtered, and dried in vacuo to give a poly(bromostyrene-acrolein-methacrylate) copolymer.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US07531297B2uspto-grants-2009_05