Reaktion #57039

ord-c49e0331450c415a8b237affb4e43f44

Reaktionsgleichung

O=c1c(-c2ccc(O)cc2)coc2cc(O)ccc12
daidzein
O=c1c(-c2ccc(O)cc2)coc2cc(O)cc(O)c12
genistein
→
O=C1c2ccc(O)cc2OCC1c1ccc(O)cc1
dihydrodaidzein
O=C1c2c(O)cc(O)cc2OCC1c1ccc(O)cc1
dihydrogenistein

Edukte

O=c1c(-c2ccc(O)cc2)coc2cc(O)ccc12
daidzein
O=c1c(-c2ccc(O)cc2)coc2cc(O)cc(O)c12
genistein

Reagenzien

[Pd]
palladium on calcium carbonate

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

Hydrogenation of daidzein and genistein using palladium on calcium carbonate as a catalyst gives dihydrodaidzein and dihydrogenistein in good yield.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US07419998B2uspto-grants-2008_09