Reaktion #56821

ord-32b171185695435ba66c8841ccdd4f78

Reaktionsgleichung

Cc1ccc(Cl)cc1-c1cc(Cl)nc(N)n1
4-chloro-6-(5-chloro-2-methyl-phenyl)-pyrimidin-2-yl-amine
Nc1ccc(Br)cc1
4-bromoaniline
Cc1ccc(Cl)cc1-c1cc(Nc2ccc(Br)cc2)nc(N)n1
title compound
Ausbeute 84.0%
Cc1ccc(Cl)cc1-c1cc(Nc2ccc(Br)cc2)nc(N)n1
N*4*-(4-Bromo-phenyl)-6-(5-chloro-2-methyl-phenyl)-pyrimidine-2,4-diamine
Ausbeute 84.0%

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

Following the method described in Example 26, 4-chloro-6-(5-chloro-2-methyl-phenyl)-pyrimidin-2-yl-amine and 4-bromoaniline provided the title compound (84% yield). 1H NMR (DMSO-d6) δ 2.35 (s, 3H, CH3), 6.10 (s, 1H, Ar), 6.45 (s, 2H, NH2), 7.31 (d, 1H, J=8.3 Hz, Ar), 7.37 (dd, 1H, J=8.2 Hz, J=2.3 Hz, Ar), 7.41 (d, 1H, J=2.3 Hz, Ar), 7.43-7.45 (m, 2H, Ar), 7.78-7.75 (m, 2H, Ar), 9.35 (s, 1H, NH).

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US07419984B2uspto-grants-2008_09