Reaktion #550578

ord-fedc18279f2c41e39a7646f546a1f17a

Reaktionsgleichung

CCOC(=O)C(=NOC)C(C)(OCC)OCC
Ethyl 2-methoxyimino-3,3-diethoxybutyrate
Br.c1cc[nH+]cc1
pyridinium hydrobromide
CCOC(=O)C(=NOC)C(CBr)(OCC)OCC
ethyl 2-methoxyimino-3,3-diethoxy-4-bromobutyrate

Lösungsmittel

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

Ethyl 2-methoxyimino-3,3-diethoxybutyrate (syn isomer, 10.0 g), pyridinium hydrobromide perbromide (15.5 g) and tetrahydrofuran (100 ml) were treated in a similar manner to that of Example 8 (2) to give ethyl 2-methoxyimino-3,3-diethoxy-4-bromobutyrate (syn isomer, 16.20 g).

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US04518774uspto-grants-1985_05