Reaktion #550410

ord-cba93a504bdd4f51b1ef958023422467

Reaktionsgleichung

CC(=O)Nc1ccc(SCCCCOc2cc3c(cc2[N+](=O)[O-])NC(=O)OC3(C)C)cc1
6-[4-(4-acetamido-phenylmercapto)-butoxy]-7-nitro-4,4-dimethyl-4H-3,1-benzoxazin-2-one
OO
hydrogen peroxide
→
CC(=O)Nc1ccc(S(=O)CCCCOc2cc3c(cc2[N+](=O)[O-])NC(=O)OC3(C)C)cc1
6-[4-(4-Acetamido-phenylsulfinyl)-butoxy]-7-nitro-4,4-dimethyl-4H-3,1-benzoxazin-2-one

Edukte

CC(=O)Nc1ccc(SCCCCOc2cc3c(cc2[N+](=O)[O-])NC(=O)OC3(C)C)cc1
6-[4-(4-acetamido-phenylmercapto)-butoxy]-7-nitro-4,4-dimethyl-4H-3,1-benzoxazin-2-one
OO
hydrogen peroxide

Reagenzien

Keine

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

Prepared analogously to Example 2 from 6-[4-(4-acetamido-phenylmercapto)-butoxy]-7-nitro-4,4-dimethyl-4H-3,1-benzoxazin-2-one and hydrogen peroxide.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US04518597uspto-grants-1985_05