Reaktion #54429

ord-f9568d0913d747759d9f7dba71709d95

Reaktionsgleichung

O=[N+]([O-])C=Cc1ccc(Br)cc1
p-bromo-β-nitrostyrene
CN(C)C(=S)[S-].C[NH2+]C
dimethylammonium dimethyldithiocarbamate
→
CN(C)C(=S)SC(C[N+](=O)[O-])c1ccc(Br)cc1
p-bromo-α-(nitromethyl)benzyl dimethyldithiocarbamate

Edukte

O=[N+]([O-])C=Cc1ccc(Br)cc1
p-bromo-β-nitrostyrene
CN(C)C(=S)[S-].C[NH2+]C
dimethylammonium dimethyldithiocarbamate

Reagenzien

Keine

Lösungsmittel

S=C=S
carbon disulfide

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

As in Example 17, reaction of p-bromo-β-nitrostyrene with dimethylammonium dimethyldithiocarbamate in the presence of carbon disulfide gave p-bromo-α-(nitromethyl)benzyl dimethyldithiocarbamate melting at 70° C.-81° C. when recrystallized without heating from acetone-ethanol solution.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US04148795uspto-grants-1979_04