Reaktion #54428

ord-8a19f64f6ff1479983d8d5d6710b90b6

Reaktionsgleichung

COc1ccc(C=C[N+](=O)[O-])cc1
p-methoxy-β-nitrostyrene
CN(C)C(=S)[S-].C[NH2+]C
dimethylammonium dimethyldithiocarbamate
→
COc1ccc(C(C[N+](=O)[O-])SC(=S)N(C)C)cc1
p-methoxy-α-(nitromethyl)benzyl dimethyldithiocarbamate

Edukte

COc1ccc(C=C[N+](=O)[O-])cc1
p-methoxy-β-nitrostyrene
CN(C)C(=S)[S-].C[NH2+]C
dimethylammonium dimethyldithiocarbamate

Reagenzien

Keine

Lösungsmittel

S=C=S
carbon disulfide

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

As in Example 17, reaction of p-methoxy-β-nitrostyrene with dimethylammonium dimethyldithiocarbamate in the presence of carbon disulfide gave p-methoxy-α-(nitromethyl)benzyl dimethyldithiocarbamate melting at 86° C.-89° C. when recrystallized without heating from acetone-ethanol solution.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US04148795uspto-grants-1979_04