Reaktion #54423

ord-5ad114d4af5b45c98cdcf588a68fc2c3

Reaktionsgleichung

CC(=O)Oc1ccc(C=C[N+](=O)[O-])cc1
4-acetoxy-β-nitrostyrene
CN(C)C(=S)[S-].C[NH2+]C
dimethylammonium dimethyldithiocarbamate
→
CC(=O)Oc1ccc(C(C[N+](=O)[O-])SC(=S)N(C)C)cc1
4-acetoxy-α-(nitromethyl)benzyl dimethyldithiocarbamate

Edukte

CC(=O)Oc1ccc(C=C[N+](=O)[O-])cc1
4-acetoxy-β-nitrostyrene
CN(C)C(=S)[S-].C[NH2+]C
dimethylammonium dimethyldithiocarbamate

Reagenzien

Keine

Lösungsmittel

S=C=S
carbon disulfide

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

As in Example 17, reaction of 4-acetoxy-β-nitrostyrene with dimethylammonium dimethyldithiocarbamate in the presence of carbon disulfide gave 4-acetoxy-α-(nitromethyl)benzyl dimethyldithiocarbamate melting at 116° C.-118° C. after recrystallization without heating from acetone-methanol solution.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US04148795uspto-grants-1979_04