Reaktion #54165

ord-2c3362a3307a47ea9c6544fd41777bc6

Reaktionsgleichung

CC1=CC(O)CC(C)(C)C1
isophorol
CC(=O)OCC1(O)C=CCC(C)(C)C1
(1-hydroxy-3,3-dimethyl-cyclohex-5-en-1-yl)-methyl acetate
→
C=C1C=CCC(C)(C)C1
1-Methylene-3,3-dimethyl-cyclohex-5-ene

Edukte

CC1=CC(O)CC(C)(C)C1
isophorol
CC(=O)OCC1(O)C=CCC(C)(C)C1
(1-hydroxy-3,3-dimethyl-cyclohex-5-en-1-yl)-methyl acetate

Reagenzien

Keine

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

1-Methylene-3,3-dimethyl-cyclohex-5-ene was prepared by the procedure given in Bull. Soc. Chim. France 4170 (1972) starting from isophorol. Its conversion into (1-hydroxy-3,3-dimethyl-cyclohex-5-en-1-yl)-methyl acetate was performed as follows:

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US04147672uspto-grants-1979_04