Reaktion #539232

Reaktionsgleichung

n-pentane

tert-butyl fluoride

n-pentane

tert-butyl fluoride

→

tert-butyl fluoride n-pentane

Reaktionsbedingungen

Aufarbeitung

1. 1
   Sonstigekept at 0° C.
2. 2
   workup.ADDITIONwas poured in a glass
3. 3
   Sonstigewas also kept at 0° C
4. 4
   workup.ADDITIONThe solution was mixed thoroughly
5. 5
   Sonstigewas kept in the refrigerator at 0° C

Vorschrift

Approximately 220 mL of cold n-pentane kept at 0° C. was poured in a glass graduated cylinder. To the n-pentane was added approximately 1.7 mL of tert-butyl fluoride which was also kept at 0° C. The solution was mixed thoroughly and analyzed by CAP-GC using the CGSB (Canadian General Standards Board, 3.0 14.3-99) method for gasoline. The concentration of tert-butyl fluoride was 0.615 vol %. The solution was kept in the refrigerator at 0° C. Lower concentrations of the tert-butyl fluoride-n-pentane stock solution was obtained by diluting with pentane. To obtain 0.45 vol % of tert-butyl fluoride, 60.5 mL of n-pentane was added to 159.5 mL of the stock solution.

Quelle