Reaktion #535902

Reaktionsgleichung

4-bromonaphthalene-1,8-dicarboxylic anhydride

1-heptyloctylamine

→

title compound

Ausbeute 63.0%

N-(1-heptyloctyl)-4-bromonaphthalene-1,8-dicarboximide

Ausbeute 63.0%

Lösungsmittel

ethylene glycol

methanol

water

Reaktionsbedingungen

Aufarbeitung

1. 1
   ExtraktionThe aqueous solution was extracted with diethyl ether
2. 2
   Trocknenthe solution was dried over MgSO4
3. 3
   Sonstigethe solvent was evaporated
4. 4
   SonstigeThe resulting yellow oil was purified by column chromatography with dichloromethane as the eluent, which

Vorschrift

5 g (18 mmol) of 4-bromonaphthalene-1,8-dicarboxylic anhydride were heated to 160° C. with 6.1 g (27 mmol) of 1-heptyloctylamine in 50 ml of ethylene glycol for 4 hours. The resulting solution was allowed to cool to room temperature. Thereafter, the solution was diluted with 50 ml of methanol and 50 ml of distilled water. The aqueous solution was extracted with diethyl ether, the solution was dried over MgSO4 and the solvent was evaporated. The resulting yellow oil was purified by column chromatography with dichloromethane as the eluent, which afforded 5.5 g (63%) of the title compound as a colorless oil.

Quelle