Reaktion #53171

ord-9019dfc024614f648ef0003d5d3d4837

Reaktionsgleichung

CCOC(=C1C(=O)Nc2ccc([N+](=O)[O-])cc21)c1ccccc1
3-(1-ethoxy-1-phenyl-methylidene)-5-nitro-2-indolinone
CCOC(=O)CN(c1ccc(N)cc1)S(C)(=O)=O
4-(N-ethoxycarbonylmethyl-N-methylsulphonyl-amino)-aniline
→
CCOC(=O)CN(c1ccc(N/C(=C2\C(=O)Nc3ccc([N+](=O)[O-])cc32)c2ccccc2)cc1)S(C)(=O)=O
(Z)-3-{-[4-(N-ethoxycarbonylmethyl-N-methylsulphonyl-amino)-phenylamino]-1-phenyl-methylidene}-5-nitro-2-indolinone

Edukte

CCOC(=C1C(=O)Nc2ccc([N+](=O)[O-])cc21)c1ccccc1
3-(1-ethoxy-1-phenyl-methylidene)-5-nitro-2-indolinone
CCOC(=O)CN(c1ccc(N)cc1)S(C)(=O)=O
4-(N-ethoxycarbonylmethyl-N-methylsulphonyl-amino)-aniline

Reagenzien

Keine

Lösungsmittel

CN(C)C=O
DMF

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

Prepared analogously to Examples 89 and 187 from 3-(1-ethoxy-1-phenyl-methylidene)-5-nitro-2-indolinone and 4-(N-ethoxycarbonylmethyl-N-methylsulphonyl-amino)-aniline in DMF.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US06855710B2uspto-grants-2005_02