Reaktion #53077

ord-f70733d128bf4738a5ceca7d7148153e

Reaktionsgleichung

COC(=C1C(=O)N(C(C)=O)c2ccc([N+](=O)[O-])cc21)c1ccccc1
1-acetyl-3-(1-methoxy-1-phenyl-methylidene)-5-nitro-2-indolinone
COc1ccc(N)cc1
4-methoxyaniline
→
COc1ccc(N/C(=C2\C(=O)Nc3ccc([N+](=O)[O-])cc32)c2ccccc2)cc1
(Z)-3-[1-(4-methoxyphenylamino)-1-phenyl-methylidene]-5-nitro-2-indolinone

Edukte

COC(=C1C(=O)N(C(C)=O)c2ccc([N+](=O)[O-])cc21)c1ccccc1
1-acetyl-3-(1-methoxy-1-phenyl-methylidene)-5-nitro-2-indolinone
COc1ccc(N)cc1
4-methoxyaniline

Reagenzien

Keine

Lösungsmittel

ClCCl
dichloromethane
N
ammonia

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

Prepared analogously to Example 77 from 1-acetyl-3-(1-methoxy-1-phenyl-methylidene)-5-nitro-2-indolinone and 4-methoxyaniline in dichloromethane and methanolic ammonia.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US06855710B2uspto-grants-2005_02