Reaktion #523478

Reaktionsgleichung

Cadmium acetate dihydrate

triethylammonium 2-trichloromethyloxazolidine-3-carbodithioate

→

Cadmium Bis (2-trichloromethyl-3-oxazolidinecarbodithioate)

Lösungsmittel

ethanol

Reaktionsbedingungen

Aufarbeitung

1. 1
   Sonstigeat 30° C
2. 2
   FiltrationThe precipitate was filtered off at 5° C.
3. 3
   Waschenwater-washed on the filter
4. 4
   SonstigeAfter drying in a vacuum desiccator
5. 5
   Sonstigethere was obtained 12.8 g

Vorschrift

Cadmium acetate dihydrate (6.7g., 0.025 mole) was stirred into a solution of 18.4g. (0.050 mole) of triethylammonium 2-trichloromethyloxazolidine-3-carbodithioate in 300 ml. of 95% ethanol at 30° C. The precipitate was filtered off at 5° C. and water-washed on the filter. After drying in a vacuum desiccator, there was obtained 12.8 g. of white crystals, melting at 223°-225° C. with decomposition. Its infra-red spectrum confirmed the desired structure and was essentially the same as that of the corresponding zinc and copper salts.

Quelle