Reaktion #522341

Reaktionsgleichung

CH3ONa

triacetonamine

→

2,2,6,6-tetramethylpiperidine-4-spiro-oxirane

Lösungsmittel

CH3CN

Reaktionsbedingungen

Aufarbeitung

1. 1
   workup.WAITin half an hour
2. 2
   workup.ADDITIONwas gradually added
3. 3
   workup.STIRRINGAfter having stirred the mixture for 4 hours at room temperature
4. 4
   workup.DISTILLATIONmost of the solvent was distilled under vacuum and 500 cc of H2O
5. 5
   workup.ADDITIONwere added to the mixture

Vorschrift

44.55 g (0.825 mole) of CH3ONa were then added, under stirring, to the mixture and then, in half an hour, a solution of 77.5 g (0.5 mole) of triacetonamine dissolved in 50 cc of CH3CN was gradually added. After having stirred the mixture for 4 hours at room temperature, most of the solvent was distilled under vacuum and 500 cc of H2O were added to the mixture.

Quelle