Reaktion #52112

Reaktionsgleichung

Oxygen

N-hydroxyphthalimide

cumene hydroperoxide

cyclododecane

→

Cyclododecanol

cyclododecanone

cyclododecane

Reaktionsbedingungen

Aufarbeitung

1. 1
   Temperaturan attached reflux condenser

Vorschrift

2 mmol of N-hydroxyphthalimide and 4 mmol of cumene hydroperoxide are added at a temperature of 130° C. to 200 mmol of cyclododecane in a round-bottomed flask having an attached reflux condenser. Oxygen at approximately 15 l/h is passed through the reaction mixture for 8 hours at said temperature. Cyclododecanol is obtained at a selectivity of 17% and cyclododecanone at a selectivity of 43%, at a cyclododecane conversion rate of 49%.

Quelle