Reaktion #52111

Reaktionsgleichung

N-hydroxyphthalimide

di-tert-butyl peroxide

cyclooctane

→

Cyclooctanol

cyclooctanone

cyclooctane

Reaktionsbedingungen

Aufarbeitung

1. 1
   Temperaturan attached reflux condenser

Vorschrift

2 mmol of N-hydroxyphthalimide and 4 mmol of di-tert-butyl peroxide are added at a temperature of 130° C. to 200 mmol of cyclooctane in a round-bottomed flask having an attached reflux condenser. Air at approximately 15 l/h is passed through the reaction mixture for 8 hours at said temperature. Cyclooctanol is obtained at a selectivity of 15% and cyclooctanone at a selectivity of 43%, at a cyclooctane conversion rate of 51%.

Quelle