Reaktion #52109

Reaktionsgleichung

N-hydroxyphthalimide

cumene hydroperoxide

cyclopentadecane

→

Cyclopentadecanol

cyclopentadecanone

cyclopentadecane

Reaktionsbedingungen

Aufarbeitung

1. 1
   Temperaturan attached reflux condenser

Vorschrift

2 mmol of N-hydroxyphthalimide and 4 mmol of cumene hydroperoxide are added at a temperature of 130° C. to 200 mmol of cyclopentadecane in a round-bottomed flask having an attached reflux condenser. Air is passed at approximately 15 l/h through the reaction mixture for 8 hours at said temperature. Cyclopentadecanol is obtained at a selectivity of 19% and cyclopentadecanone at a selectivity of 48%, at a cyclopentadecane conversion rate of 46%.

Quelle