Reaktion #52106

Reaktionsgleichung

N-hydroxyphthalimide

cumene

→

acetophenone

2-phenyl-2-propanol

Ausbeute 13.1%

phenol

Ausbeute 10.4%

cumene

Reaktionsbedingungen

Aufarbeitung

1. 1
   Temperaturan attached reflux condenser

Vorschrift

0.3 mmol of N-hydroxyphthalimide and 0.3 mmol of Co(II) acetate are added at a temperature of 125° C. to 30 mmol of cumene in a round-bottomed flask having an attached reflux condenser. The reaction mixture is stirred for 8 hours at said temperature under an oxygen atmosphere of 1 bar. Not the target product, but acetophenone is obtained at a selectivity of 58.7%, 2-phenyl-2-propanol (13.1%) and phenol (10.4%) at a cumene conversion rate of 49.3%.

Quelle