Reaktion #52105

Reaktionsgleichung

N-hydroxyphthalimide

1-cyclohexylbenzyl hydroperoxide

cyclohexylbenzene

→

1-cyclohexylbenzene hydroperoxide

cyclohexylbenzene

Reaktionsbedingungen

Aufarbeitung

1. 1
   Temperaturan attached reflux condenser

Vorschrift

0.3 mmol of N-hydroxyphthalimide and 0.6 mmol of 1-cyclohexylbenzyl hydroperoxide are added at a temperature of 110° C. to 30 mmol of cyclohexylbenzene in a round-bottomed flask having an attached reflux condenser. The reaction mixture is stirred for 8 hours at said temperature under an oxygen atmosphere of 1 bar. 1-cyclohexylbenzene hydroperoxide is obtained at a selectivity of 96.2% at a cyclohexylbenzene conversion rate of 28.6%.

Quelle