Reaktion #50857

ord-c9abef9a5c4546839e88ada6111053af

Reaktionsgleichung

C[CH2][Al]([Cl])[CH2]C
Et2AlCl
CCCCCCC
heptane
[H][H]
hydrogen
→
C=CCCCC
1-hexene
C=CCCCCC=C
1,7-octadiene

Edukte

C[CH2][Al]([Cl])[CH2]C
Et2AlCl
CCCCCCC
heptane
[H][H]
hydrogen

Reagenzien

Keine

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    Sonstigewas bubbled through the reaction mixture

Vorschrift

A solution of 985.94 grams (11.715 mole) 1-hexene and 58.24 grams (0.4831 mole) 1,7-octadiene (molar charge ratio 96:4) in 450 grams of heptane was polymerized with Et2AlCl (13.5 millimoles) and AATiCl3 (6.97 millimoles) at 25° C. for 20 hours. During the course of the reaction, hydrogen was bubbled through the reaction mixture. The conversion of the polymer was 62 percent, inherent viscosity was 1.6 dl/gram. The composition of monomers in the copolymer was 97.8:2.2 mole ratio from NMR analysis.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US05428209uspto-grants-1995_06