Reaktion #502064

ord-7e11e4253b7d44f2a2c4ac9c3e72ef63

Reaktionsgleichung

O=C([O-])[O-].[Ag+2]
Silver carbonate
O=S(=O)(O)CS(=O)(=O)O
methanedisulfonic acid
O=C([O-])[O-].[Ag+2]
silver carbonate
O=C=O
carbon dioxide
→
O=S(=O)([O-])CS(=O)(=O)[O-].[Ag+2]
silver methanedisulfonate
Ausbeute 123.7%

Edukte

O=C([O-])[O-].[Ag+2]
Silver carbonate
O=S(=O)(O)CS(=O)(=O)O
methanedisulfonic acid
O=C([O-])[O-].[Ag+2]
silver carbonate
O=C=O
carbon dioxide

Reagenzien

Keine

Lösungsmittel

O
water

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    Sonstigeany remaining insoluble material was removed by filtration
  2. 2
    Sonstigewas removed under vacuum

Vorschrift

Silver carbonate (20 g, 0.0725 moles) was added to methanedisulfonic acid (25.55 g 50% solution in water) and diluted in 25 mL of distilled water while stirring. The silver carbonate dissolved with effervescence of carbon dioxide. After the reaction was complete, any remaining insoluble material was removed by filtration and the filtrate was stripped of water was removed under vacuum to give 25.3 g of pure silver methanedisulfonate.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US08088548B2uspto-grants-2012_01