Reaktion #502058

Reaktionsgleichung

toluene

sulfuric acid

n-butanol

→

n-Butyl Acrylate

Reaktionsbedingungen

Aufarbeitung

1. 1
   SonstigeA typical cleavage reaction
2. 2
   workup.ADDITIONby dispersing 0.1602 g
3. 3
   SonstigeSolvent was removed by rotary evaporation under reduced pressure
4. 4
   workup.ADDITIONThe residual solid was dispersed into 100 mL CHCl3
5. 5
   Extraktionextracted with water three times
6. 6
   Sonstigeto remove any sulfuric acid
7. 7
   FiltrationThe organic dispersion was filtered through a 0.2 μm Nylon membrane
8. 8
   Waschenwashed with CHCl3
9. 9
   workup.DISTILLATIONThe filtrate was distilled under reduced pressure
10. 10
    Sonstigeto remove the solvent
11. 11
    Sonstigedried in vacuum overnight at 40° C

Vorschrift

A typical cleavage reaction was performed by dispersing 0.1602 g GCNF-PBA3 into 100 mL toluene followed by adding 100 mL n-butanol and 5 mL concentrated sulfuric acid and refluxing the mixture at 100° C. for 9 days. Solvent was removed by rotary evaporation under reduced pressure. The residual solid was dispersed into 100 mL CHCl3 and extracted with water three times to remove any sulfuric acid. The organic dispersion was filtered through a 0.2 μm Nylon membrane and washed with CHCl3. The filtrate was distilled under reduced pressure to remove the solvent and dried in vacuum overnight at 40° C. Molecular weight and polydispersity of the cleaved PBA were measured by GPC. (Mw=31,300, Mw/Mn=1.73)

Quelle