Reaktion #499690

ord-cb5f92a66fae4325a924ce2b1426830e

Reaktionsgleichung

[Cl-].[Cl-].[Cl-].[Cl-].[Zr+4]
zirconium tetrachloride
[Cl][Ti]([Cl])([Cl])[Cl]
titanium tetrachloride
ClCCl
methylene chloride
→
[Cl-].[Cl-].[Cl-].[Cl-].[Cl][Ti]([Cl])([Cl])[Cl].[Zr+4]
TiCl4 ZrCl4

Edukte

[Cl-].[Cl-].[Cl-].[Cl-].[Zr+4]
zirconium tetrachloride
[Cl][Ti]([Cl])([Cl])[Cl]
titanium tetrachloride
—
Zr nitro
ClCCl
methylene chloride

Reagenzien

Keine

Lösungsmittel

C[N+](=O)[O-]
nitromethane

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

1.4 g (6.0 mmol) of zirconium tetrachloride and 10.207 g (53.8 mmol) of titanium tetrachloride were placed in a two-necked round-bottomed flask under an argon atmosphere. 480 ml of methylene chloride and 7 ml (7.89 g) of nitromethane were added (ratio Zr/nitro compound 1:21.5).

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US06562916B2uspto-grants-2003_05